4 Ways Decaf Coffee is Made

Decaf coffee starts its life as regular coffee. The caffeine is removed from the unroasted, green coffee beans long before they are ever roasted. There isn't just one way to do this; several methods exist to separate the caffeine from the bean. This guide lists the four primary ways decaffeinated coffee is produced for the Australian market, from common solvent-based techniques to completely chemical-free processes.
1. The Direct-Solvent Process
This is a very common and effective method for making decaf coffee. It uses a solvent, typically methylene chloride or ethyl acetate (a compound found naturally in some fruits), which is very good at bonding with caffeine molecules. The process is straightforward and carefully controlled to meet Australian food safety standards.
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The green coffee beans are first steamed to open their pores.
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Next, the beans are repeatedly rinsed with the solvent for several hours. The solvent acts like a magnet, pulling the caffeine out of the beans.
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The caffeine-filled solvent is then drained away.
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Finally, the beans are steamed and dried again to ensure any remaining solvent is removed.
2. The Indirect-Solvent Process
As the name suggests, this method ensures the solvent never actually touches the coffee beans. It is a slightly more complex process that focuses on moving the caffeine out of the beans and into a separate body of water first.
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A batch of green coffee beans is soaked in hot water. This causes the caffeine and other flavour components to leach out into the water.
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The beans are then removed from the water and set aside.
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The solvent is added to this water. It bonds with the caffeine molecules, and the two are separated from the water.
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The result is a flavourful, caffeine-free water solution. The original coffee beans are soaked in this solution again to reabsorb the flavours and aromas they initially lost.
3. The Swiss Water Process
The Swiss Water Process is a popular chemical-free option for decaffeination in Australia, especially in the specialty coffee market. It relies solely on water, temperature, and carbon filtration to gently remove caffeine.
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A batch of green coffee beans is soaked in hot water, creating a flavour-rich solution called Green Coffee Extract (GCE). This first batch of beans is discarded.
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The GCE is then passed through a series of special carbon filters that are specifically sized to capture only the larger caffeine molecules.
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This creates a caffeine-free GCE that is completely saturated with all the desirable coffee flavour compounds.
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New batches of coffee beans are then soaked in this GCE. Because the GCE is already full of flavour, it cannot absorb any more from the beans. Instead, only the caffeine migrates from the beans into the GCE, resulting in decaffeinated coffee that retains its original taste.
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4. The Carbon Dioxide (CO2) Process
This is a highly effective and natural decaffeination method that uses CO2, the same gas that makes drinks fizzy. When put under intense pressure, CO2 becomes a liquid and acts as a selective solvent for caffeine.
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Water-soaked green coffee beans are placed inside a large, high-pressure container.
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Liquid CO2 is circulated through the container, where it naturally dissolves the caffeine molecules while leaving the larger flavour molecules within the beans.
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The caffeine-rich CO2 is then pumped into a separate chamber.
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In this chamber, the pressure is released. The CO2 returns to its gaseous state and evaporates, leaving behind the extracted caffeine. The clean CO2 is then recaptured and reused for the next batch.

Does the Method Change the Taste?
Many people worry that decaf coffee will taste flat, but this is largely a myth with modern techniques. While any process can slightly alter a coffee's profile, methods like the Swiss Water Process and the CO2 method are excellent at preserving the bean's original character. The most important factor in a delicious cup of decaf is the quality of the initial green coffee bean. A great bean will make great decaf.
How Much Caffeine is Left in Decaf?
No decaf coffee is 100% free of caffeine, but the amount left is extremely small. A typical cup of regular coffee from an Australian café might have 80-120 milligrams of caffeine. By comparison, a cup of decaf coffee will usually have only 2-5 milligrams. This tiny amount has a negligible effect on most individuals.
Make Your Decaf Coffee Amazing
The four main ways to make decaf coffee are the direct-solvent, indirect-solvent, Swiss Water Process, and CO2 method. Each process removes caffeine from unroasted beans and can produce a full-flavoured cup.
Modern chemical-free methods are particularly good at protecting the coffee's original taste profile. As a consistent supplier, we carefully select our decaf coffee to ensure it provides a delicious and satisfying experience. Knowing these options can help you find the decaf you will enjoy the most.
Contact us to partner with The Blind Coffee Roaster for the best residential and commercial coffee solutions.
Frequently Asked Questions About How Decaf Coffee is Made
What Is The Healthiest Way To Decaffeinate Coffee?
The Swiss Water Process and the CO2 method are widely considered the healthiest options because they are completely chemical-free. These methods use natural elements—water and carbon dioxide—to remove caffeine, which appeals to many health-conscious Australian consumers.
Is Decaf Coffee Full Of Chemicals?
Not all decaf coffee is. While some common methods use chemical solvents like ethyl acetate or methylene chloride, these are almost entirely removed from the final product to meet strict food safety standards. If you are concerned about chemicals, simply choose a coffee that specifies it was decaffeinated using the Swiss Water Process or the CO2 method.
Is Decaf Coffee Just Coffee Without Caffeine?
Essentially, yes. It begins as regular coffee, and the decaffeination process is designed to remove nearly all the caffeine while leaving the hundreds of other flavour and aroma compounds intact. It still contains the natural elements that give coffee its distinct taste and body.
Why Do People Drink Decaf?
Australians choose decaf for many reasons. Some are sensitive to caffeine and want to avoid jitters, anxiety, or disrupted sleep. Others may need to limit their caffeine intake due to pregnancy or a medical condition. Many people simply love the ritual and taste of coffee and want to enjoy a cup in the afternoon or evening without the stimulant effect.
What Are The Two Main Methods Of Decaffeination?
The two main categories are solvent-based methods, which use agents like ethyl acetate to remove caffeine, and non-solvent-based methods. The most popular non-solvent methods are the Swiss Water Process, which uses a flavour-charged water solution, and the CO2 method, which uses pressurised carbon dioxide.
Does Decaf Coffee Still Have Health Benefits?
Yes, it does. Decaf coffee retains most of the antioxidants found in regular coffee, which are known to have various health benefits. It offers many of the same advantages as regular coffee, just without the stimulating effects of caffeine.
